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Foundations · No. 9Newtonian & Non-Newtonian

Foundations — viscosity that moves

When one viscosity number isn’t enough

For water, viscosity is one number. For paint, grease, and blood, it depends on how hard you push — and one number becomes a trap.

By Medrado Analytical Innovations · Foundations, No. 9 · for the working analyst

In this piece · 2 min read
  1. Viscosity, defined by shear
  2. When the line bends
  3. Measuring a fluid that moves

Ask how thick water is and the question has one answer: its viscosity is a fixed number at a given temperature, no matter how gently or hard you stir it. Water is Newtonian. Ask how thick paint is, and the honest answer is a question back: how fast are you moving it? Paint is thin under a brush and thick on the wall. That is non-Newtonian behaviour, and for a whole class of everyday fluids, a single viscosity number is incomplete, and so misleading.

Viscosity, defined by shear

Newton pictured a fluid as stacked layers and defined viscosity as the ratio of the shear stress you apply to the shear rate it produces.1 For a Newtonian fluid that ratio is constant: push twice as hard, it flows twice as fast, and the viscosity is the same number either way. Plot shear stress against shear rate and you get a straight line through the origin whose slope is the viscosity. One line, one number.

When the line bends

For a non-Newtonian fluid the line is not straight, and the "viscosity" you read depends on where on the curve you measured. The common kinds are worth naming:

Shear-thinning (pseudoplastic) fluids thin as you push harder — paint, polymer solutions, ketchup, blood. The most common non-Newtonian behaviour, and the reason a VI-improved oil can be thinner in a bearing than on the bench. Shear-thickening (dilatant) fluids do the opposite and stiffen under stress — a cornstarch-and-water suspension is the kitchen example. Thixotropic fluids thin over time under shear and rebuild at rest, so their history matters. And a Bingham plastic will not flow at all until a yield stress is exceeded — toothpaste holds its shape until you squeeze.

Why this breaks a single number

Report "the viscosity of the grease is X" and you have said almost nothing, because X is only true at the one shear rate you happened to measure. A pump, a bearing, and a settling tank each impose wildly different shear rates, and the grease has a different effective viscosity in each. For a non-Newtonian fluid, a viscosity value with no shear rate attached — and for thixotropic fluids, no time or history — is not a measurement anyone can use.

Measuring a fluid that moves

This is why a capillary viscometer, which measures at essentially one shear rate, is fine for a Newtonian oil but not for a paint. A rotational viscometer or rheometer shears the fluid at a range of rates and traces the whole flow curve, which is the description a non-Newtonian fluid needs.2 Density and its pairings still tell you what a fluid is; for how it flows, the shear rate is part of the answer.

Before you trust a viscosity number, ask whether the fluid is Newtonian. If it is — most light oils, solvents, fuels — one number is enough. If it is not, one number is a headline with the story missing, and the shear rate is the story.

Check yourself

Answer in your head first, then open the answer. Any question can go into your Quiz me.

  1. How did Newton define viscosity?

    Show the answer
    “the ratio of the shear stress you apply to the shear rate it produces.”

    See it in the article ·

  2. What do shear-thinning fluids do?

    Show the answer
    “Shear-thinning (pseudoplastic) fluids thin as you push harder”

    See it in the article ·

  3. Why is a capillary viscometer fine for an oil but not for a paint?

    Show the answer
    “a capillary viscometer, which measures at essentially one shear rate, is fine for a Newtonian oil but not for a paint.”

    See it in the article ·

Glossary

Newtonian
A fluid whose viscosity is a single number at a given temperature, independent of shear rate.
Non-Newtonian
A fluid whose viscosity changes with shear rate, so one number cannot describe it.
Shear rate
How fast adjacent layers of fluid slide past each other — the speed gradient across the fluid.
Shear stress
The force per unit area applied to slide one layer over another.
Shear-thinning (pseudoplastic)
Thins under stress — paint, polymer solutions, blood.
Shear-thickening (dilatant)
Stiffens under stress — cornstarch suspensions.
Thixotropic
Thins over time under shear and recovers at rest — greases, gels.
Bingham plastic / yield stress
Behaves as a solid until a minimum (yield) stress is exceeded, then flows — toothpaste, grease.
Rotational viscometer / rheometer
Shears a fluid over a range of rates to map its whole flow curve.

Sources

  1. Newton (Principia, 1687) described a fluid’s resistance as proportional to the rate of shearing; the modern definition of viscosity as shear stress over shear rate follows from it. See standard rheology references (e.g. Barnes, Hutton & Walters, An Introduction to Rheology) for the non-Newtonian models (power-law, Carreau) that describe a full flow curve.
  2. ASTM D2196, Rheological Properties of Non-Newtonian Materials by Rotational Viscometer; ASTM D445 / D7042 assume Newtonian behaviour and report a single viscosity.
  3. Companion articles: Foundations No. 4 (density and viscosity) and No. 8 (viscosity index).