MAI-Alchemy · Analytical Chemistry, Taught by Practice

The Analytical Column

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Foundations · No. 29Titration

Foundations · free to read

What an oil's numbers are telling you

Picture an oil analysis report on your desk. The acid number says 1.5 (milligrams of potassium hydroxide per gram of oil, the standard way of keeping score). Is that good or bad? The honest answer is that it depends, and the reason why is the most useful thing to know about reading these reports.

Start from where the oil began

A brand-new oil already has an acid number before it has done a minute of work. Some of the additives that protect your equipment react in the test as if they were acids. So the number on its own tells you very little. What matters is how far it has moved from where that oil started, measured by the same lab, the same way.

An acid number of 1.5 means one thing for an oil that started at 0.3 and something quite different for an oil that started at 1.2. Much of the rise over time comes from the oil slowly oxidising as it ages, and it speeds up with heat and with water getting in.

There is no magic number

People often want one number that says "change the oil now". There is not one that fits every machine. The standards organisations say such limits should be set from experience, and oil-analysis specialists suggest a practical way to do it: watch the oil's own history, and act when a result breaks away from the pattern that oil has been following.

That pattern matters because acid number often stays almost flat for a long time and then starts to climb, once the protective additives are used up. The climb is the warning. Some guidance gives starting points for particular equipment, and your equipment maker's recommendations come first.

Check before you act

The test itself has real scatter, so a single high result is a reason to look again, not to panic. Check the sample was labelled right and tested by the usual method. Re-run it, or take a fresh sample from the same point. Ask whether something got into the system, or whether a different oil was used to top it up. A real ageing trend rises steadily, sample after sample. A single spike usually has another cause.

Keep the method the same

A trend only means something if every point was measured the same way. Labs occasionally update their methods, and a change in method can show up as a sudden step in the numbers that has nothing to do with the oil. If your results suddenly look better overnight, ask the lab whether anything changed.

Why this matters to you

These reports are cheap insurance, but only when they are read as a story rather than a single snapshot. Know where the oil started, watch where it is heading, confirm surprises, and keep the measuring stick the same.

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References

  1. E. Zabawski (TestOil), "Setting Acid Number and Base Number Limits", CBM Connect, 2020.
  2. ExxonMobil, Turbine Oil Condition Monitoring, technical training guide.
  3. OELCHECK, "Standard for AN (Acid Number)", OELCHECKER, spring 2019.